Authors: Franke, E.K.; Birnie, D.P. III
Source: Journal of Materials Science Letters 14 (1995)
1807-1809
Abstract: Spin coating is in general a convenient method and
reproducible method for applying highly uniform thin films to substrates
of all kinds. It starts by dispensing the precursor solution onto the chosen
wafer, the rotation is initiated, causing most of the solution to be rapidly
flung from the substrate by inertia. During fluid flow and thinning stages,
there will be strong inertial forces that create both shear and elongational
fields in the fluid. This paper investigates whether these shear and stretching
gradients can be effective at causing preferential fiber orientation when
spin coating of composite solutions is performed. It is shown that fibers
in a composite solution orientate themselves with a general radial orientation
during spin coating. The largest fraction of fibers align themselves to
within 15o of their ideal radial orientation.